Our hoods have a solvent trap at the front in case of large spills, it's a stainless steel grate covering a large, high surface area secondary steel trap below. Ngl, I pour smaller amounts of pure volatiles in there to evaporate. Usually < 10 mL. Small volumes with dissolved solids get dumped in the glass waste container in the hood to evaporate before disposal too.

Not the best practice, but the pragmatic approach.

Larger volumes go to proper waste containers. Local EHS mostly just dilutes things before pouring it down the drain. Not much we can do about that, so I opt for greener solvents from the beginning wherever possible.